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Black Holes: Phase Transitions
With the discovery of Stephen Hawking in 1974 that black holes will
evaporate through quantum effects, it became possible to conduct
thermodynamic thought experiments in which a black hole is enclosed in
a box, in equilibrium with its own radiation. A simple Schwarzschild
black hole is not that interesting, because it has no free parameters,
apart from its mass. Although you can change the size of the box and
the total energy of the system, the first-order phase transition that
you can observe is always qualitatively the same.
The two other free parameters of a black hole are its angular momentum and its charge. It is difficult to use the angular momentum, since a rotating black hole cannot be brought into complete equilibrium with an enclosing box if the box is too large, since that would require the box to rotate faster than the speed of light. That is why I chose to enclose a charged black hole in a box, in a paper that I wrote a few years after Hawking's discovery:
In this simple system I found a wealth of thermodynamical effects, including the possibility of first-order phase transitions and a meaningful way to talk about phase diagrams and a critical point. Various heat capacities could be calculated, some of which exhibited discontinuities, again hinting at the presence of phase transitions.
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